The acids from autoxidation of methyl linoleate have been analyzed as their methyl esters by combined capillary gas chromatography‐mass spectrometry (GC‐MS). The principal components were hexanoic, trans‐2‐octenoic, suberic and azelaic acid. Minor components included formic, pentanoic, heptanoic, trans‐2‐heptenoic, octanoic and nonanoic acid. In addition,trans‐2,3‐epoxy‐octanoic acid was isolated as its methyl ester by preparative GLC and was identified by means of NMR, high resolution MS, IR and by conversion to a known derivative.
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Horvat et al. (1969) studied this question.
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