Principles and examples of assembling heteroleptic supramolecular cluster compounds of copper subgroup metals based on polydentate phosphine ligands of various topologies are considered. The choice of an organic linker between phosphorus atoms allows one to control the formation of three-dimensional aggregates with a regular architecture, whereas the choice of alkynyl ligands determines their luminescent properties.
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Elena V. Grachova (2019) studied this question.
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