Phosphine metal–organic frameworks (P-MOFs) are an emerging class of coordination polymers that provide novel opportunities for metal–supported catalysis as solid ligands. Here, we present the synthesis and characterization of three novel P-MOFs based on a (diphenylphosphino)terephthalic acid linker. We targeted the structures of MOF-5, MIL-101(Cr), and MIL-101(Al)-NH 2 to produce materials with partial diphenylphosphine substitution, which were crystalline and highly porous.
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Morel et al. (2014) studied this question.
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