Submonolayer phases of Pb on Si(111)

We present conclusive results on the structures and coverages of the submonolayer phases of Pb on the Si(111) 7×{}7 surface based on scanning-tunneling-microscopy, low-energy-electron-diffraction, and Rutherford backscattering measurements. For room-temperature deposition at low coverage on the 7×{}7 surface, we find that Pb atoms occupy sites above and between the Si adatoms (with a preference for the faulted half of the unit cell) leaving the 7×{}7 structure intact. After annealing to 450 ^∘{}C, some Pb atoms occupy Si(111) 7×{}7 adatom sites, while others have nucleated to form small areas of an unusual {}3 ×{} {}3 phase which has a 1:1 ratio of Si:Pb.