Ordered Ba(B1/3′B2/3″)O3 ceramics are currently used as dielectric resonators for microwave and millimeter wave technologies. The degree of ordering is generally determined by x-ray techniques. In this work, we demonstrate that Raman spectroscopy can be used to evaluate the degree of long-range order of these materials. We also show how varying the degree of order of samples allows partial assignment of the optical vibrational modes.
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Moreira et al. (2001) studied this question.
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