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According to theoretical considerations of Staverman 2 the molecular weight of a substance can be determined by means of osmometry even when the membrane is permeable to the solute of which the molecular weight must be determined.In this case the reflection coefficient of the membrane for the solute must be determined separately.The feasibility of the method is demonstrated by a molecular weight determination of sucrose from osmometry with membranes highly permeable to sucrose.
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Talen et al. (1965) studied this question.
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