The incomplete cubane-type cluster, [Mo3S4(H2O)9]4+, and the complete cubane-type cluster, [Mo3NiS4(H2O)9Cl]3+, are incorporated into 12-membered ring zeolites by ion exchange, leading to catalysts which are highly selective for C2 formation from CO–H2.
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Taniguchi et al. (1995) studied this question.
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