⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

January 1, 1995Synlett

1,2-Stereoinduction in β-Oxy-Radicals: The Influence of the α-Substituent

Bernd Giese Michel Bulliard Joachim Dickhaut Ralf Halbach Carla Haßler Ursula Hoffmann Berthold Hinzen Martin Senn

View at Publisher

Ask AI

Bookmark

Share

Abstract

All articles of this category 1,2-Stereoinduction is studied in H-abstraction reactions of acyclic radicals with a methyl and a tert -butyldiphenylsiloxy group at the stereogenic center. The extent of the stereoselectivity depends significantly upon the substituent at the radical center. 1,2-stereoinduction - β-oxy-radicals - A-strain - Felkin-Anh rule

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Giese et al. (1995) studied this question.

synapsesocial.com/papers/6aa6706686a9fcb24992392a https://doi.org/10.1055/s-1995-4867

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 related papers. Consider them for comparative context:

1Development and Application of Chiral Binaphthyldimethyl η6-Benzene Ruthenium CatalystsSynlett · Fri,
2Humidity-driven Polymorph Control during Industrial Drying of Ivabradine HydrochlorideSynlett · Fri,
3Scalable and Catalytic Asymmetric Synthesis of Atorvastatin from Chiral β-lactoneSynlett · Mon,
4Palladium-catalyzed Fujiwara-Moritani Reaction with VinylsilanesSynlett · Mon,
5Microwave-Enhanced Asymmetric Oxidative Lactonization of meso-DiolsSynlett · Fri,

More from Synlett

Base-Free Palladium-Catalyzed Synthesis of 2-Alkoxy-1,3-Dienes from Primary Propargyl Carbonates with Benzyl AlcoholsThu,
Base-Regulated Divergent Synthesis of Acetamides from Dioxazolones and Phosphorus YlidesThu,
Cobalt Metallaphotoredox-Catalyzed Radical Phosphinylation of Alkenes to Access Allylic Phosphine OxidesTue,
Employing Late-Stage Functionalization Strategies to Address Metabolic Challenges in Drug DiscoveryTue,
Chemistry of CO2 to Bridge a Prebiotic Chemistry and Organic SynthesisTue,