The compound [Mn(S2CNC4H8O)3]I5·0.5CH2Cl2 has been prepared by reaction of tris(morpholine-carbodithioato-S,S′)manganese(III), [Mn(S2CNC4H8O)3], with iodine in CH2Cl2 solution. The crystal structure has been determined by X-ray diffraction at 295 K. Crystals are monoclinic, space group P21/c, a= 20.451(9), b= 18.910(5), c= 18.714(5)Å, β= 109.68(2)°, U= 6 814(4)Å3, and Z= 8. The structure comprises anionic layers composed of chains of V-shaped I5– units interposed by differently inclined [Mn(S2CNC4H8O)3]+ cations.
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Deplano et al. (1987) studied this question.