Methods of synthesis of alkyl 2-(1-t-butylperoxyalkyl)propenoates and ethyl 2-t-butylperoxymethylbut-2-enoate are developped through the nucleophilic substitution of t-butylperoxylate anion towards various allylic derivatives prepared from alkyl 2-hydroxymethylalk-2-enoates and ethyl 2-(1-hydroxyethyl)propenoate.
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Navarro et al. (1993) studied this question.
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