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Gloeosporone, the germination self‐inhibitor from the fungus Colletotrichum gloeosporioides f.sp. jussiaea, is shown by spectroscopic data and X‐ray analysis to have the constitution and relative configuration as shown in Formula 2 (either (1S,6R,12R)‐1‐hydroxy‐6‐pentyl‐5,15‐dioxabicyclo[10.2.1]pentadecan‐4,13‐dione or its enantiomer), rather than the previously assigned constitution 1.
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Meyer et al. (1987) studied this question.
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