Organometallic fluorides of main group and transition elements are described starting with monocyclopentadienyl derivatives of the group 4 metals and their adducts with AlMe(3). Host-guest type compounds such as [(eta(5)-C(5)Me(4)Et)TiF(3)](4)CaF(2) and supramolecular assemblies such as Ag(S(4)(CN)(2))(2)AsF(6) are also observed. Finally some aluminum-fluorine compounds including derivatives of aluminum(I) are described.
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Herbert W. Roesky (1999) studied this question.
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