A Large Macrobicyclic cavity for the Selective Complexation of Alkali Metal Ions The preparation of the new ligand 3 was carried out starting with the podand 8 and the triamine 11. Ligand 3 forms complexes with alkali metal ions in solution (chloroform) as well as under the conditions of FAB mass spectrometry, whereby Cs⊕ selectivity is observed.
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Peter‐Katalinić et al. (1989) studied this question.
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