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In the mixed-valent complex [AgII(tmc)(BF4)][AgI6(C2 )(CF3CO2)5(H2O)]· H2O, a [AgII(tmc)(BF4)]+1∞ cationic column induces the assembly of a novel, anionic zigzag chain constructed from edge-sharing of silver(I) triangulated dodecahedra each enclosing a C22− species.
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Wang et al. (2001) studied this question.
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