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Hetero π‐Systems, 17. — Aminosilylen (Aminosilanediyl) Aminosilylene can be prepared by 254‐nm photolysis of silyl azide isolated in an argon matrix at 12 K. Subsequent irradiation with wavelengths > 300 nm yields silaisonitrile (3) and molecular hydrogen. This reaction may be reversed with 254‐nm light.
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Maier et al. (1989) studied this question.
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