WS2–Graphite Dual-Ion Batteries

A novel WS 2 –graphite dual-ion battery (DIB) is developed by combining a conventional graphite cathode and a high-capacity few-layer WS 2 -flake anode. The WS 2 flakes are produced by exploiting wet-jet milling (WJM) exfoliation, which allows large-scale and free-material loss production (i.e., volume up to 8 L h −1 at concentration of 10 g L −1 and exfoliation yield of 100%) of few-layer WS 2 flakes in dispersion. The WS 2 anodes enable DIBs, based on hexafluorophosphate (PF 6 – ) and lithium (Li + ) ions, to achieve charge-specific capacities of 457, 438, 421, 403, 295, and 169 mAh g –1 at current rates of 0.1, 0.2, 0.3, 0.4, 0.8, and 1.0 A g –1, respectively, outperforming conventional DIBs. The WS 2 -based DIBs operate in the 0 to 4 V cell voltage range, thus extending the operating voltage window of conventional WS 2 -based Li-ion batteries (LIBs). These results demonstrate a new route toward the exploitation of WS 2, and possibly other transition-metal dichalcogenides, for the development of next-generation energy-storage devices.