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September 14, 2026Fuel CellsOpen Access

Exergy‐Based Performance Analysis and Optimization of Autonomous Fuel Cell‐Based Energy Systems With Solid Oxide and Proton Exchange Membrane Fuel Cells Fed by Biogas of Variable Composition

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Authors

ETEvangelos TsiarasDMDennis MytakisFCFrank A. Coutelieris

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Overview

Thermodynamic modeling study reveals net electrical efficiencies of 48%–55% in autonomous biogas fuel cell systems, highlighting solid potential for high-efficiency off-grid power generation.

Key Points

  • To evaluate and compare the thermodynamic and exergy performance of autonomous solid oxide fuel cell (SOFC) and proton exchange membrane fuel cell (PEMFC) systems operating on biogas of varying compositions.
  • Developed a unified thermodynamic framework applying mass, energy, and exergy balances across common balance-of-plant components, including fuel processors, heat exchangers, afterburners, and fuel cell stacks.
  • Performed deterministic parametric analyses evaluating CH4/CO2 ratios of 50/50 and 90/10 while varying reformer and afterburner temperatures.
  • Net electrical efficiencies ranged from approximately 48% to 55%, with overall exergy efficiencies between 73% and 81% across evaluated configurations.
  • The highest rates of exergy destruction occurred within the fuel-processing subsystem and the electrochemical conversion stack.
  • Methane-rich biogas (90/10 CH4/CO2) substantially enhanced thermodynamic performance by increasing energy conversion efficiency and exergy utilization relative to 50/50 mixtures.

Cite This Study

Tsiaras et al. (2026) studied this question.

synapsesocial.com/papers/6aa7b42d0926e14a848b3c83https://doi.org/10.1002/fuce.70157
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