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The structure elucidation of a novel branched-chain hexasaccharide glycoside, muscaroside B, has been aided by fast atom bombardment mass spectrometry Muscaroside A—a straight-chain analogue having the same 27-norlanostane skeleton and spirofused tetrahydrofuran ring—and digitonin—a branched-chain steroidal glycoside— were used as standards.
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Adinolfí et al. (1984) studied this question.
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