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The reaction of HCO radicals with NO 2 was studied at 298 K using time-resolved infrared diode laser spectroscopy to detect CO, CO 2, and NO products. HCO was formed by the reaction of photolytically produced chlorine atoms with H 2 CO. After quantifying product yields and considering likely secondary reactions, we obtain the following product branching ratios: CO + NO + OH accounts for 63 ± 5%, and H + NO + CO 2 accounts for the remaining 37 ± 5%. Upper limits of 10% are estimated for the CO + HONO and HNO + CO 2 channels.
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Rim et al. (1998) studied this question.
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