Emission in the visible has been observed from dense, cold helium gas in contact with solid hydrogen when irradiated by a 15-MeV proton beam. All four stable isotopic combinations have been studied, and the spectrum of one of them, ⁴HeD, appears highly perturbed. Spectral identification of rotational features and a plausible explanation of the perturbation have been provided by rovibrational energy-level calculations.
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Brooks et al. (1987) studied this question.
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