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The prototype of an organometallic linear-rod building block incorporating the saturated σ-donating 16-TMC macrocycle, peripheral pyridine moieties for versatile ligation, and the π-conjugated trans-[Ru(CCpy-4)2] fragment along the molecular axis, is described and applied to the assembly of trimetallic arrays.
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Choi et al. (2000) studied this question.
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