Mechanochemical access to NDI-bridged Janus di-NHC complexes for light-driven redox-responsive catalysis

This is the authors' abstract. We don't add key points for this paper.

Mechanochemical synthesis affords NDI-bridged Janus di-NHC Rh/Ir complexes, avoiding solution-phase degradation. The redox-active NDI enables strong metal–ligand coupling and reversible electronic switching for tunable catalysis and supramolecular assembly.