Our group has designed and developed 3-alkyl-2-vinylindoles as a new type of vinylindoles, which have displayed versatile reactivity in Brønsted acid catalyzed reactions. For instance, this class of vinylindoles can act as 2C building blocks in [n+2] cyclizations, as 2,3-disubstituted indoles in dearomatizations, and as NCC building blocks in [3+2] cyclodimerizations. This article summarizes the main contributions of our group in this research field. 1 Introduction 2 As 2C building blocks in [n+2] cyclizations 3 As 2,3-disubstituted indoles in dearomatization 4 As NCC building blocks in [3+2] cyclodimerizations 5
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Shi et al. (2016) studied this question.
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