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The synthesis of vertically aligned carbon nanotubes with submillimeter-order heights was performed using ethanol chemical vapor deposition with Co catalysts supported on Al 2 O 3 substrates. The effects of Al 2 O 3 in the form of amorphous alumina and single-crystalline sapphire were investigated through a characterization of the Co catalyst particles on the substrates. An important effect of Al 2 O 3 was found to be the production of highly dense and nanosized Co particles, owing to a low surface diffusivity.
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Ohno et al. (2008) studied this question.
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