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The heat is on: A new [3+2] cycloaddition/cycloreversion strategy allows for catalytic and thermally allowed carbonyl-olefin metathesis (see scheme). This strategy opens opportunities for new developments in the field of carbonyl-olefin metathesis, which traditionally relied on stoichiometric amounts of transition-metal reagents or photochemical promotion.
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Ai‐Lan Lee (2013) studied this question.
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