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A new mathematical representation of the cluster model for dielectric relaxation, in a bound dipole case, is established by employing the extremal value theory. Two distinct probabilistic mechanisms, which drive the dielectric response function to acquire the power-law form, are presented. Consequently, two forms of self-similarity, one of which dominates the response at short times and the other at long times, leading to a general relaxation equation, are identified. Finally, the conditions under which the derived response function takes the well known empirical forms (Williams-Watts, Cole-Cole, Cole-Davidson, 'broadened' Debye, and 'flat loss' responses) are recognized.
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Weron et al. (1993) studied this question.
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