Experimental study demonstrates UV-induced photochemical reaction increases the energy barrier while shortening relaxation time in a dysprosium magnet, highlighting complex spin dynamics.
The photochemical [2 + 2] reaction on a mononuclear Dy( iii ) single-molecule magnet leads to the higher energy barrier after UV irradiation, along with the shorter magnetic relaxation time that is due to the acceleration of Raman process at low temperatures.
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Wang et al. (2017) studied this question.
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