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March 31, 2017MaterialsOpen Access

Electrodeposited Porous Mn1.5Co1.5O4/Ni Composite Electrodes for High-Voltage Asymmetric Supercapacitors

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Authors

GPGuan‐Ting PanSCSiewhui ChongTYThomas C.‐K. Yang

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Overview

Experimental study demonstrates high energy density in an asymmetric supercapacitor using Mn1.5Co1.5O4 electrodes, suggesting robust cycling stability for advanced energy storage devices.

Key Points

  • To synthesize mesoporous Mn1.5Co1.5O4/Ni composite electrodes via electrodeposition and evaluate their electrochemical performance in high-voltage asymmetric supercapacitors.
  • Synthesized mesoporous Mn1.5Co1.5O4 (MCO) films directly on nickel foam using electrodeposition for varying durations (7.5, 15, and 30 minutes) followed by annealing.
  • Assembled an asymmetric supercapacitor using the optimized (MCO/Ni)-15 min positive electrode, a plasma-treated activated carbon/Ni negative electrode, and a carboxymethyl cellulose-lithium nitrate gel electrolyte.
  • The (MCO/Ni)-15 min electrode achieved the highest capacitance compared to electrodes prepared with 7.5-minute and 30-minute deposition times.
  • Operating within a 2.0 V window, the asymmetric device delivered an energy density of 27.6 Wh·kg−1 and a power density of 1.01 kW·kg−1 at 1 A·g−1.
  • Following 5000 charge-discharge cycles, the supercapacitor maintained 96% of its energy density and 92% of its power density.

Cite This Study

Pan et al. (2017) studied this question.

synapsesocial.com/papers/6aa9eba1f92ab359461bf376https://doi.org/10.3390/ma10040370
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