Reaktion von Tetraschwefeltetranitrid mit Rhenium(VII)-chloronitrid Die Kristallstruktur von [Ph4As+ ]2 [Cl4 Re(NS)(NSCl) 2- ] · CH2 Cl2 / Reaction of Tetrasulfurtetranitride with Rhenium(VII)-chloronitride The Crystal Structure of [Ph4 As+ ]2 [Cl4 Re(NS)(NSCl)2- ] · CH2Cl2

The synthesis of [Ph4As+]2[Cl4Re(NS)(NSCl)2-] · CH2Cl2 (4) from the reaction of S4N4, Cl4ReN, and Ph4AsCl is reported. CH2Cl2 is used as solvent. The reaction of S4N4 with Re2Cl10 similarly leads to the salt [Ph4As+][Cl2ReNS-] (5) in a smaller yield. 4 crystallizes in the triclinic space group P1̅ with Z = 2, a - 10.434(2), b = 12.1454(6), c = 21.125(2) Å, a = 81.210(6), β = 86.70(1), γ = 76.624(8)°.