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Treatment of Li[H2GaR2] [R=CH(SiMe3)2] with the hydrogen peroxide adduct (H2O2)2.DABCO (DABCO=diazabicyclooctane) afforded a heterocyclic digallium peroxide, [R2Ga(micro,eta1,eta1-O2)(micro-OH)GaR2]Li(DABCO) (2), in which two dialkylgallium groups are bridged by an oxidizing peroxo and a hydroxo ligand.
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Uhl et al. (2009) studied this question.
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