Crystal structure and Hirshfeld surface analysis of 4′-chloro-5-oxo- N -phenyl-3-(thiophen-2-yl)-2,3,4,5-tetrahydro-[1,1′-biphenyl]-4-carboxamide monohydrate

The title molecule, C 23 H 18 ClNO 2 S·H 2 O, has a stable conformation with S (5) and S (6) rings formed by intramolecular C—H...S and C—H...O hydrogen bonds. The water molecule and the carboxyl oxygen atom of the main molecule also make an O—H...O hydrogen bond. In the crystal, N—H...O, O—H...Cl, O—H...O and C—H...O hydrogen bonds connect molecules to form a three-dimensional network. The molecules are further connected by C—H...π interactions and face-to-face π–π interactions into layers parallel to the (001) plane.