Deuterated methanol in the pre-stellar core L1544

Context. High methanol (CH3OH) deuteration has been revealed in Class 0 protostars with the detection of singly, doubly, and even triply D-substituted forms. Methanol is believed to form during the pre-collapse phase via gas-grain chemistry and then eventually injected into the gas when the heating produced by the newly formed protostar sublimates the grain mantles. The molecular deuterium fraction of the warm gas is thus a relic of the cold pre-stellar era and provides hints of the past history of the protostars.