Convenient and Recyclable TiO 2 /g-C 3 N 4 Photocatalytic Coating: Layer-by-Layer Self-assembly Construction on Cotton Fabrics Leading to Improved Catalytic Activity under Visible Light

In this work, a TiO 2 /g-C 3 N 4 photocatalytic coating is built on cotton fabrics with a simple layer-by-layer (LBL) self-assembly strategy in which TiO 2 and g-C 3 N 4 are alternately assembled on cotton fabrics via electrostatic attraction. The fabrics, as support, disperse TiO 2 /g-C 3 N 4 powder photocatalyst to expose more active sites. The fabrics also act as an adsorbent to boost the pollutants capture. Consequently, the coated fabrics exhibit an outstanding photocatalytic property applicable for degradation of both liquid rhodamine (RhB) and gaseous toluene pollutants. The fabric with seven bilayer coatings shows the best for RhB decomposition with degradation rate of 92.5%. Over 90% toluene could be eliminated by the photocatalytic coating under simulated sunlight irradiation. Besides, the coating fabrics show excellent stability and reusability.