We revisit and quantify in this work several aspects of Standard Model physics at finite temperature that drive the theoretical value of the cosmological parameter, the effective number of neutrinos N eff , away from 3 in the early universe. Our chief focus is finite-temperature corrections to the equation of state of the QED plasma in the vicinity of neutrino decoupling at T ∼ 1 MeV, where T is the photon temperature. Working in the instantaneous decoupling approximation, we recover at 𝒪( e 2 ), where e is the elementary electric charge, the well-established correction of δ N eff (2) ≃ 0.010 across a range of plausible neutrino decoupling temperatures, in contrast to an erroneous claim in the recent literature which found twice as large an effect. At 𝒪( e 3 ) we find a new and significant correction of δ N eff (3) ≃ −0.001 that has so far not been accounted for in any precision neutrino decoupling calculation of N eff , significant because this correction is in fact larger than—or at least comparable to—the change in N eff induced between including and excluding neutrino oscillations in the transport modelling. In addition to the QED equation of state, we make a first pass at quantifying finite-temperature QED corrections to the weak interaction rates that directly affect the neutrino decoupling process, and find in this connection that the 𝒪( e 2 ) thermal electron mass correction induces a change of δ N eff m th ≲ 10 −4 . A complete assessment of the various effects considered in this work on the final value of N eff will necessitate an account of neutrino energy transport beyond the instantaneous decoupling approximation. However, relative to N eff = 3.044 obtained in the most recent such calculation, we expect the new effects found in this work to lower the number to N eff = 3.043.
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