A new method for the synthesis and film deposition of nonvolatile aromatic lanthanide(III) carboxylates by ligand exchange reaction between the starting volatile components in the gas phase was proposed. The complexes Ln(Bz)3 (Ln = La3+, Tb3+, Lu3+, HBz = benzoic acid) were synthesized by gas-phase ligand exchange reaction between the volatile Ln(Thd)3 and HBz (HThd = 2,2,6,6-tetramethylheptane-3,5-dione). The composition of the complexes was confirmed by elemental, thermal, IR-spectroscopic, and photoluminescence analyses and, in the case of lanthanum and lutetium complexes, by 1H NMR.
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Kotova et al. (2007) studied this question.
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