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September 10, 2026Journal of Asian Ceramic SocietiesOpen Access

Growth of and anisotropic lithium ion diffusion in TiNb 2 O 7 single crystals

Naruto Imano Kensuke Matsumura Muneyasu Suzuki Ikuo Yanase Shohei Kodama Hiroaki Takeda

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Abstract

Transparent and light-yellow TiNb2O7 (TNO) single crystals with a maximum thickness of approximately 3 mm were grown from a melt. This study used the grown crystals to experimentally demonstrate that lithium diffusion parallel to the b-axis was favorable for lithium diffusion in TNO. Lithium was successfully doped (Li+ insertion) into the TNO single crystals using a liquid-type cell with metallic Li as the negative electrode. Arrhenius plots of the Li-doped TNO crystals revealed that the activation energies for [010] (//b-axis) and [10 [Formula: see text]] (⊥b-axis) were approximately 0.28 and 0.73 eV, respectively.

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Cite This Study

Imano et al. (2026) studied this question.

synapsesocial.com/papers/6aadd425d8a136f6c7b8a97a https://doi.org/10.1080/21870764.2026.2725477

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