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The physical principles of laser spectral analysis of the relative content of ortho- and para-water molecules, which is aimed at studying the spin-selective processes in gaseous media, are considered. An analyzer of the content of water spin isomers is described. It is based on a tunable diode laser and implies high-precision measurement of the near-IR absorption in vibrational-rotational lines of the H 2 O molecule. The efficiency of the diagnostic method developed is demonstrated in the diagnostics of spin-selective adsorption in nanoporous polymer sorbents. There was confirmed the existence of the effects of spin-selective adsorption of ortho- and para-water molecules, which had been previously observed by only submillimeter spectroscopy.
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Stepanov et al. (2010) studied this question.
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