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Three-dimensional assembly of enantiopure D-camphoric acid and in situ synthesized tetradentate 1,2,4,5-tetra(4-pyridyl)benzene (TPB) ligand with tetrahedral Zn(2+) leads to a new homochiral four-connected luminescent material from which the novel TPB ligand can be isolated in the hydrated crystalline form.
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Zhang et al. (2008) studied this question.
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