Oxidative pillaring: The intercalation of a molecular pillar (Me2DABCO2+) into synthetic Cs-tainiolite, which shows sufficient intracrystalline reactivity by an oxidative cation-exchange mechanism, yields a material with microporosity that resembles zeolites in both narrow pore size distribution and total pore volume. Owing to the high structural Fe content, this pillared clay provides a size-selective, shape-selective, and electronically conducting framework.
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Baumgärtner et al. (2008) studied this question.
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