Anomalous susceptibility in single crystals of EuCo 2 Si 2 with trivalent Eu: Influence of excited J multiplets

We present a detailed study on the physical properties of single crystals of the Eu 3+ intermetallic EuCo 2 Si 2 . The Eu valence was confirmed by X‐ray absorption. At low temperatures, the anisotropic susceptibility can be explained by a Eu 3+ Van Vleck contribution with a crystal field parameter V₂⁰ = 355\, K , but at high temperatures the data exceed the Van Vleck values significantly. This excess susceptibility is possibly related to the magnetic exchange between the excited Eu multiplets and the conduction band. A γ of 9.6 mJ K −2 mol and a Debye temperature of 322 K were estimated from the low temperature specific heat data. The compound does not undergo any phase transition in the temperature range 2–300 K.