Liquid−liquid equilibrium data are critical for designing the extraction equipment or calculating the thermodynamic limit of a given separation. In this work, the LLE data were measured for the cyclohexane + (benzene, + toluene, + ethylbenzene, or + o -xylene) + 4-methyl- N -butyl pyridinium tetrafluoroborate ([bmpy]BF 4 ) systems at 303.15 K under atmospheric pressure. The consistency of the measured LLE data was tested using the Othmer−Tobias correlation and the root-mean-square deviation (rmsd) in the mass fraction of [bmpy]BF 4 in the lower phase and the average value of the absolute difference (AAD) between experimental mass fraction of cyclohexane in the upper phase and that calculated using the Othmer−Tobias correlation.
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Abu-Eishah et al. (2008) studied this question.
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