The concept of separation capacity in isotachophoresis has been investigated in order that the analytical separation possibilities may be predicted for given working conditions. A relationship has been derived between the amount and composition of a binary mixture under isotachophoretic separation and the amount of electricity which has to be passed through the system to obtain complete separation of the mixture. By using this relationship, values of the separation capacity have been calculated for three two-component mixtures analyzed by means of two isotachophoretic instruments and verified experimentally.
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Boček et al. (1978) studied this question.
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