A neutron-diffraction study has been carried out on KH2PO4 at 16.5kbars and 10K, close to the point at which the transition temperature, Tc, falls to OK at 17.1kbars. The results suggest that under these conditions, the H atoms are still disordered over two sites with a separation, δ, of 0.22(2)Å. Comparison with results from previous structural studies of other other H-bonded systems suggests that Tc is linearly related to δ in each case and that each system has the same critical value of δ as Tc ↪
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Nelmes et al. (1991) studied this question.
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