Effect of separation and acidification of cattle slurry on ammonia volatilization and on the efficiency of slurry nitrogen for herbage production

SUMMARY During the growing season of 1988 at the Agricultural Research Institute, Hillsborough, cattle slurry was kept whole or was separated through screens with mesh sizes of 5 mm, 3 mm, 0·25 mm and 0·015 mm. The resulting slurry liquids were either left unacidified or were acidified to pH 5.5 with 5M-H2SO4 prior to application at 75 kg NH+4-N/ha to perennial ryegrass in the field. Volatilization of ammonia was measured using ventilated enclosures. Plots treated with a range of rates of inorganic fertilizer N were used to construct response curves to assess the efficiency of N in slurry for herbage production compared with equinitrogenous inorganic fertilizer. On average over the season, acidification of cattle slurry decreased ammonia volatilization to < 15% of that from unacidified whole slurry. Compared with inorganic fertilizer N, the overall efficiency of NH+4-N was 96% in acidified slurries and 36% in unacidified whole slurry. Ammonia volatilization from separated slurries decreased with decreasing mesh size to 39% of that from whole slurry for a 0·015 mm mesh. The overall efficiency of NH4+-N in slurry separated through a 0·015 mm mesh was 76%. A highly significant linear relationship was found between NH3-N volatilized from all slurry treatments and N offtake in herbage at all three harvests.