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The novel complexes trans-[Ru(dppe)2(C≡CR)(C≡P)] (R = CO2Me, C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis studies.
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Trathen et al. (2014) studied this question.
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