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The physical and spectral properties of five previously undisclosed diazirines substituted with electron‐withdrawing groups are described. The halo‐diazirines yield the respective divalent carbon species and nitrogen on pyrolysis. The cyanofluoro‐, fluoro‐methoxy‐ and fluorodifluoramino‐carbenes form the respective cyclopropanes with tetra‐fluoroethylene. The intramolecular reactions of difluoramino‐substituted carbenes are also discussed. The ultraviolet spectra are presented.
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Mitsch et al. (1965) studied this question.
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