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Sodium-and silver-ion exchange in single crystals of two polymorphous modifications of the Na 3 Sc 2 (PO 4 ) 3 compound has been studied. It is established that in the process of ion exchange, the samples undergo phase transitions similar to the well-known temperature transformations observed in these systems. It is shown that the phases with ferroelectric, ionic, and superionic properties may simultaneously coexist in one sample.
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Shilov et al. (2005) studied this question.
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