The structure of the sex pheromone produced by the male sandfly Lutzomyia longipalpis, from the Jacobina region of Brazil, previously proposed tentatively as the novel homosesquiterpene 3-methyl-α-himachalene is confirmed by synthesis and biological activity; the relative stereochemistry is defined as 1RS,3RS,7RS by comparing the natural product with the four synthetic diastereoisomers.
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Hamilton et al. (1999) studied this question.
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