The terminal carbido ligand of (PCy3)2(Cl)2RuC coordinates to other metal centers in a σ-donor fashion, as in (PCy3)2(Cl)2RuC–Pd(Cl)2(SMe2) and (PCy3)2(Cl)2RuC–Mo(CO)5.
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Hejl et al. (2002) studied this question.
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