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An unexpected Ru(dmso) 3 -supported heptatungstovanadate fragment [HVW 7 O 28 Ru(dmso) 3 ] 6− (1) is reported, representing the novel binding mode of the Ru-coordination to a tungstovanadate framework via Ru–O–W and Ru–O–V bonds.
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Bi et al. (2010) studied this question.
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